Normally stable, even under fire conditions. $14.00. Page 2 of 11 Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. This section provides a listing of alternate names for this chemical, Keep unopened Hazard statements (GHS US) : H225 - Highly flammable liquid and vapor H311 - Toxic in contact with skin Precautionary statements (GHS US) : P210 - Keep away from heat, sparks, open flames, hot surfaces. Follow Us On. A mixture of acetone and CHLOROFORM in a residue bottle exploded. Quality Management Dossier; Operational Excellence Dossier; SDS; CoA; Certificates ; Material Qualification Dossier; Synonyms: TCM, Trichloromethane, Methane trichloride, Methyl trichloride EC Number: 200-663-8 Hill Formula: CHCl₃ CAS #: 67-66-3 Chemical Formula: CHCl₃ … Move container from fire area. Chloroform, or trichloromethane, is an organic compound with formula C H Cl 3.It is a colorless, strong-smelling, dense liquid that is produced on a large scale as a precursor to PTFE.It is also a precursor to various refrigerants. GHS06, GHS08. CAS# 67-66-3. CHLOROFORM: CHLOROFORM: Hazard Class: 6.1: 6.1(9.2) UN Number: UN1888: UN1888: Packing Group: III: III: Section 15 - Regulatory Information US FEDERAL TSCA CAS# 67-66-3 is listed on the TSCA inventory. Number of Components Comps. %PDF-1.5 %���� USA.gov. All liquid chemicals have been tested between approximately 20°C and H302 Harmful if swallowed. An inadequately cooled addition of sodium to a chloroform-methanol mixture (sodium methoxide) caused a violent explosion, [MCA Case History No. Chloroform GR for analysis (for determinations with dithizone). Dermal contact. It is subject to revision as (EPA, 1998). Hazard Symbol 1 Chloroform, ACS Safety Data Sheet WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm - www.P65Warnings.ca.gov Poison/Toxic Material. Common Name. Hazard statements are assigned to a class and category and describe the nature of the hazard of a chemical including, where appropriate, the degree of hazard. P241 - Use explosion-proof electrical, ventilating, lighting equipment. Liq. Gases Under Pressure - Compressed gas GHS Label Elements Symbol(s) Signal Word Warning Hazard Statement(s) Contains gas under pressure; may explode if heated. Controlled Substances:Psychoactive Drugs/Narcotic Drugs/Hypertoxic Chemicals/Non-Medical Use of Narcotic Drugs and Psychotropic Substances. Fight fire from maximum distance. Chloroform. Certified Secure. Container may explode in the heat of fire. Chloroform for spectroscopy Uvasol®. If fabric P233 - Keep container tightly closed. Chloroform CAS 67-66-3 for analysis EMPARTA® ACS - Find MSDS or SDS, a COA, data sheets and more information. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) –Lead, cadmium, chloroform, tetrachloroethylene and other chlorinated solvents • Effects on the reproductive system –Various pesticides, lead, ethylene oxide • Cancers –Ethylene oxide, benzene, various pesticides, some chlorinated solvents, many cytotoxic agents Health Impacts of Chemical Exposure . It is a colorless, strong-smelling, dense liquid that is produced on a large scale as a precursor to PTFE. 3. H336 May cause drowsiness or dizziness. Explosive Material Hazard. # M-502-13-10X. : Chloroform: 10 lbs. : 1888 IMCO Class No. : 67-66-3 Product code : LC13040 Formula : CHCl3 Synonyms : 1,1,1-trichloromethane / Chloroform / formyl trichloride / freon 20 / methane trich loride / methane, trichloro- / methenyl chloride / methenyl trichloride / methyl trichloride / R 20 / R 20 The toxic material symbol indicates the presence of substances that may harm an individual if they enter the body. S-phrase(s) S36/37 Wear suitable protective clothing and gloves. CAS# 25377-72-4 is listed on the TSCA inventory. Less<< Chloroform MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Limited evidence of a carcinogenic effect. H351 Suspecte d of causing cancer. Chloroform-D | CHCl3 | CID 71583 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. It has caused rapid death attributable to cardiac arrest and delayed death from liver and kidney damage. Safety hazard symbol notice Documentation needs to be consulted in all cases where the symbol is used to find out the nature of the potential hazard and any actions which have to be taken. including, without limitation, no warranties of merchantability or fitness Price (USD) Price. - No smoking. It is a human suspected carcinogen. 2 EU-DSD / DPD Indication(s) of danger and R phrase(s) Highly flammable R11 3.2 Label elements EU-GHS / CLP Hazard pictogram(s)/Symbols. Hazard Symbol 1 Chloroform, ACS Safety Data Sheet WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm - www.P65Warnings.ca.gov Add to Cart Add. Correct technical name: CHLOROFORM Sea transport: UN-No: 1888 IMDG class: 6.1 III Correct technical name: CHLOROFORM Air transport: UN-No: 1888 IATA/ICAO class: 6.1 III Correct technical name: CHLOROFORM 15. R40 Limited evidence of a carcinogenic effect. these chemicals are present. Incid. Chloroform SARA 313 toxic chemical notification and release reporting: Chloroform CERCLA: Hazardous substances. H351 Suspected of causing cancer. Slightly soluble in water. temperature. Eye contact. May cause damage to the liver or kidneys through prolonged or repeated inhalation. This material contains Chloroform (CAS# 67-66-3, 99+%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. It is a powerful anesthetic, euphoriant, anxiolytic and sedative when inhaled or ingested. SECTION 14 - TRANSPORT INFORMATION IATA Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing Group: III IMO Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing Group: III RID/ADR Shipping Name: CHLOROFORM Hazard Class: 6.1 UN Number: 1888 Packing group: III SECTION 15 - REGULATORY INFORMATION European/International Regulations … GHS Chloroform Labels (79665) Chloroform: Harmful if inhaled or swallowed. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 Chloroform is a volatile chlorinated organic solvent whose vapors have a narcotic effect. All chemicals have DuPont believes to be reliable. It is incompatible with dinitrogen tetraoxide, fluorine, sodium metal and alcohols, nitromethane, and triisopropylphosphine. Concentration Conc. Chloroform CAS 67-66-3 EMPROVE® ESSENTIAL - Find MSDS or SDS, a COA, data sheets and more information. Chloroform CHCl3 Page 1 Section 1: Chemical Product Product Name: Chloroform CAS Number: 67-66-3 EC Number: 212-742-4 UN Number: 1888 Synonym: Trichloromethane, Formyl Trichloride, Methane Trichloride, Methyl Trichloride, Methenyl Trichloride, TCM, Freon 2,Cloroformio , Chloroforme , Хлороформ Chemical Name: Chloroform Repeated exposure to 77-237 ppm has caused lassitude, dullness, urinary frequency, and gastrointestinal disturbances. R 40 Limited evidence of a carcinogenic effect. It reacts vigorously with acetone in the presence of potassium hydroxide or calcium hydroxide. 2 mg/mL. Health Hazard: A cancer-causing agent (carcinogen) or substance with respiratory, reproductive, or organ toxicity that causes damage over time (a chronic, or long-term, health hazard). The laboratory boots required safety symbol indicates when street shoes are not adequate for certain lab-related tasks.… - Find MSDS or SDS, a COA, data sheets and more information. for a particular use and assume no liability in connection with any use of Workers may be … This information is not intended as a license to operate of DuPont or others covering any material or its use. The Uvasol® solvents range has been specially designed for spectroscopy and other applications requiring solvents of the highest spectral purity. determine the level of toxicity and the proper personal protective Serged and bound seams are degraded by some hazardous liquid Unless otherwise stated, permeation was measured for single chemicals. Clean Air Act: CAS# 67-66-3 is listed as a hazardous air pollutant (HAP). Hazard statement(s) H302 Harmful if swallowed. of garment to avoid potential exposure to chemical. Harmful substances GHS-Pictogram old danger symbol Harmful substances have a moderate risk of health damages if taken up … Catalog Number Cat. Office of Response and Restoration, This can be suppressed by adding ethanol as a stabilizer. Causes skin irritation. from the permeation behavior of the individual chemicals. 3 Effective date : 01.06.2015 Page 1 of 7 Sodium Hydroxide,10.0N Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Other sources include pulp and paper mills, hazardous waste sites, and sanitary landfills. 67-66-3. and risk. More>> Chloroform for gas chromatography ECD and FID SupraSolv®. EINECS: This product is on the European Inventory of Existing Commercial Chemical Symbol. Due to its light sensitivity, it may undergo degradation with time. Specific hazards during firefighting : The product is not flammable. , ( Contains: Nitrogen , Chloroform ) Hazard Class: 2.2 UN#: UN1956 Required Label(s): 2.2 International Bulk Chemical Code This material contains one or more of the following chemicals required by the IBC Code to be identified as dangerous chemicals in bulk. additional knowledge and experience are gained. Probable oral lethal dose for humans is 0.5 to 5 g/kg (between 1 ounce and 1 pint) for a 150 lb. Gastrointestinal signs and symptoms include nausea, vomiting, salivation, anorexia, and gastrointestinal irritation. Chloroform can be toxic if inhaled or swallowed. Chloroform::::: 1 . Acute exposure may also lead to respiratory depression, chemical pneumonitis, pulmonary edema, metabolic acidosis, central nervous system depression, headache, fatigue, and dizziness. Dissolves in water to form a corrosive solution of hypochlorous acid which decomposes on standing to chlorine, oxygen, and chloric acid. Carbon tetrachloride, also known by many other names (such as tetrachloromethane, also recognised by the IUPAC, carbon tet in the cleaning industry, Halon-104 in firefighting, and Refrigerant-10 in HVACR) is an organic compound with the chemical formula CCl 4.It is a colourless liquid with a "sweet" smell that can be detected at low levels. 4/2/2009. h�b```��,�E cb��M��U����]���),�eUk5�g`066��l�� ���aeb��HG�%��NqŪ\��&�ct������::8::@\�����`�00��E�0qؖ�#��!$�������A"a�B��"b�~E��j� �.��1�\rA^���5X�iQ�"F���X�N i��,@� vw8s Anyone intending to use this information should first verify Chloroform is use as a solvent for fats, oils, rubber, alkaloids, waxes, gutta-percha, resins; as cleansing agent; in fire extinguishers to lower the freezing temperature of carbon tetrachloride. 2.3 3. 27°C unless otherwise stated. Examples for substances with the above-described properties are chloroform (trichloromethane = carcinogenic), benzene (carcinogenic) and 1,2-dimethoxyethane = ethyleneglycol dimethyl ether (toxic … Chloroform (CHCl 3 ) is a colorless liquid that quickly evaporates into gas. Receptacle form: Thin mouth glass bottle: Hazard symbols: Signal word: Danger: Symbol Mark: The preservation method: Toxicity data: LD50 908mg/kg taking orally Rat U.S. - RCRA (Resource Conservation & Recovery Act) - Basis for Listing - Appendix VII Included in waste streams: F024, F025, F039, K009, K010, K019, K020, K021, K029, K073, K116, K149, K150, K151, K158 (Chloroform) . Click here for verification of our PCI DSS status. Cardiac arrhythmias and cardiac arrest have been reported. Substance name : Chloroform CAS-No. including trade names and synonyms. Acetone deuterated Hazard symbols. Chloroform sc-239527 Hazard Alert Code Key: EXTREME HIGH MODERATE LOW Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Chloroform STATEMENT OF HAZARDOUS NATURE CONSIDERED A HAZARDOUS SUBSTANCE ACCORDING TO OSHA 29 CFR 1910.1200. evaluation under their specific end-use conditions, at their own discretion The information in CAMEO Chemicals comes from a variety of data sources. Shipping Name: COMPRESSED GAS, N.O.S. : 6.1 Packing Group: III Hazardous Statement: H302-H315-H319-H331-H336-H351-H361d-H372 Precaution Statement: P261-P281-P305 + P351 + P338-P311 Risk Statement: 20/22-36/38-40-48/20-63 Safety Statement: 36/37 Dimethyl sulfoxide deuterated N/A. It appears that your browser has JavaScript disabled. HAZARDS … Storage Condition Storage. are damaged, end user should discontinue use Suspected of damaging fertility or the unborn child. Suspected of causing cancer. Other OSHA standards that generally apply to hazardous substances include the Hazard Communication standard and the Respiratory Protection standard . (method A and B) or ASTM D6978 test methods. seams and closures have shorter breakthrough times and higher permeation 693]. 2 Serious eye Irritation Eye Irrit. Exposure to decomposition products may be a hazard to health. H373 May cause damage to organs through prolonged or repeated exposure. Belongs to the Following Reactive Group(s). For example, the hazard statement ‘Toxic if swallowed’ is the hazard statement for Acute toxicity category 3 (Oral). Chloroform-D | CHCl3 | CID 71583 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. 1. A different temperature may have significant influence on the Irritating to skin. rates than the fabric. COVID-19 is an emerging, rapidly evolving situation. It is the user's responsibility to The mean lethal dose is probably near 1 fluid ounce (44 g). Causes serious eve irritation. 24. chloroform structure. performance of fabrics, not complete garments, under controlled conditions. Hazard Symbols:-----Risk Phrases: 24/25 34 CAS#: 108-95-2 Chemical Name: Phenol %: 45-55% EINECS#: 203-632-7 Hazard Symbols: T ... N.O.S. Specific hazards arising from the chemical (e.g., nature of any hazardous combustion products): Carbon oxides expected to be the primary hazardous combustion product Special protective equipment and precautions for fire fighters: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. H225 Highly flammable liquid and vapour. Eng. It is practically not flammable at lower temperatures. Hazard symbol(s) R-phrase(s) R22 R38 R40 R48/20/22 Harmful if swallowed. CAS 67-66-3, chemical formula CHCl₃. Considerations specific to the 2424 Evaporative Light Scattering Detector Power cord replacement hazard Waters contact information Contacting medium Information In the past, it was used as anesthetic. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur R 48/20/22 Harmful : danger of serious damage to health by prolonged exposure through inhalation and if swallowed. stated. Email. CAS No. Exposure to decomposition products may cause a health hazard. 0 R48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. May displace oxygen and cause rapid suffocation. For chances to WIN FREE products and receive coupons! Potassium iodide can block absorption of radioactive iodine by the thyroid gland through flooding the thyroid with non-radioactive iodine and preventing intake of radioactive molecules, thereby protecting the thyroid from cancer causing radiation. Chloroform explodes when in contact with aluminum powder or magnesium powder or with alkali metals (e.g., lithium, sodium, and potassium) and dinitrogen tetroxide. Compare. Emergency overview Hazards identification Routes of entry Potential acute health effects Toxic by inhalation. S-phrase(s) S36/37 Wear suitable protective clothing and gloves. CAUTION: This information is based upon technical data that Hazard Class and Category Code(s) Flammable liquid Flam. Precautionary Statement(s) 39(1968)]. It is one of the four chloromethanes and a trihalomethane. 2.0 mg/mL in MeOH. Matrix. Sigma-Aldrich offers a number of Chloroform-d products. View information & documentation regarding Chloroform-d, including CAS, MSDS & more. Web site owner: National Oceanic and Atmospheric Administration. becomes torn, abraded or punctured, or if seams or closures fail, or if Exposure to chloroform may also cause cancer. MATERIALS SAFETY DATA SHEET (MSDS) Ethanol (C 2 H 5 OH) MSDS Number NCP/P/1 Version number Version No: 6.0 Date issued 20th August 2018 Next Review date August 2020 Page No. Burning pain and corneal epithelium injury may occur from chloroform liquid splashed in the eye. Toxicity and Safe Handling Please refer to the current Safety Data Sheet (SDS) prior to working with chloroform. CAS 67-66-3, chemical formula CHCl₃. this information. guarantee of results and assumes no obligation or liability... "X" indicates that this is a second name for an EPCRA section 313 chemical already included on this consolidated list. A clear colorless liquid with a characteristic odor. chemicals, such as strong acids, and should not be worn when attached gloves, visors, etc. Chloroform AH049-4 Version 1.1 1 Revision Date 08/24/2017 Print Date 08/24/2017 4/14 Carbon dioxide (CO2) Foam Cool closed containers exposed to fire with water spray. Unit. Some animal studies also show evidence of reproductive and developmental toxicity from chloroform exposure. Ambient (>5 °C) Typical Chromatogram TC. When heated it liberates phosgene, hydrogen chloride, chlorine and toxic and corrosive oxides of carbon and chlorine. The information set forth herein reflects laboratory Additional UPS-imposed hazardous material charge. 2290 0 obj <>/Filter/FlateDecode/ID[<3E08AA8C5B703D4DBAA6BD7F37C98C50><0C97D76832D25A4CB15137DFB26BA312>]/Index[2272 27]/Info 2271 0 R/Length 91/Prev 317317/Root 2273 0 R/Size 2299/Type/XRef/W[1 2 1]>>stream Potassium Iodide is a metal halide composed of potassium and iodide with thyroid protecting and expectorant properties. Overview. Irritating to respiratory system. ... in connection with this information. Ethanol is a primary alcohol that is ethane in which one of the hydrogens is substituted by a hydroxy group. Normalized breakthrough times Irritating to skin. Will not burn under typical fire conditions. [MCA Case History 1661(1970)]. H315 Causes skin irritation. COVID-19 is an emerging, rapidly evolving situation. - Find MSDS or SDS, a COA, data sheets and more information. Signs and Symptoms of Chloroform Exposure: Signs and symptoms of acute exposure to chloroform vapor may include conjunctivitis and blepharospasm (twitching of the eyelid). Related Pages. NFPA SUPPLIER Company: Santa Cruz Biotechnology, Inc. R 34 Causes burns. Chemical Details: Stabilized : Chemical CAS Number: 67-66-3 : Chemical Formula: CHCl 3: Chemical Formula Weight: F.W. May also indicate that the same chemical with the same CAS number appears on another list with a different chemical name. Used as a solvent, to make other chemicals, as a fumigant. MATERIALS SAFETY DATA SHEET (MSDS) Ethanol (C 2 H 5 OH) MSDS Number NCP/P/1 Version number Version No: 6.0 Date issued 20th August 2018 Next Review … FS9100000. National Ocean Service, R 40 Limited evidence of a carcinogenic effect. Explosive material hazard – It pertains to chemicals in the lab that has … (EPA, 1998), It is classified as moderately toxic. Hazard Symbols: T C Risk Phrases: R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. 119.38 : Chemical Specs: Assay (CHCl 3) Min. CAS 67-66-3, chemical formula CHCl₃. Click here for verification of our veteran owned status. This material does not contain any Class 1 Ozone depletors. Hazard identification Highly flammabl e. May form explosive peroxides. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. The addition will increase the polarity of the solvent and potentially impact certain applications. Section 2 - HAZARDS IDENTIFICATION Classification in accordance with paragraph (d) of 29 CFR 1910.1200. Nonflammable under most conditions, but burns under extreme conditions. It is one of the four chloromethanes and a trihalomethane.It is a powerful anesthetic, euphoriant, anxiolytic and sedative when inhaled or ingested. Since addition of acetone to chloroform in the presence of base will result in a highly exothermic reaction, it is thought that a base was in the bottle. … CHLOROFORM: CHLOROFORM: Hazard Class: 6.1: 6.1(9.2) UN Number: UN1888: UN1888: Packing Group: III: II: Section 15 - Regulatory Information US FEDERAL TSCA CAS# 67-66-3 is listed on the TSCA inventory. relative humidity per military standard MIL-STD-282. Hazard pictogram(s)/Symbols. endstream endobj 2273 0 obj <>/Metadata 61 0 R/Outlines 77 0 R/PageLayout/OneColumn/Pages 2268 0 R/StructTreeRoot 192 0 R/Type/Catalog>> endobj 2274 0 obj <>/ExtGState<>/Font<>/XObject<>>>/Rotate 0/StructParents 0/Type/Page>> endobj 2275 0 obj <>stream DOT ID & Guide . Chloroform Deuterated Hazard symbols. R36/38 Irritating to eyes and skin. 67-66-3 RTECS No. News 32:258(1954); UL Bull. chloroform. The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. Dike fire control water for later disposal; do not scatter the material. Wear self-contained breathing apparatus and special protective clothing. R 38 Irritating to skin. Symbol: GHS06, GHS08: Signal Word: Danger Hazard Statements: H302-H315-H319-H331-H336-H351-H361d-H372: Precautionary Statements: P261-P281-P305 + P351 + P338-P311 Can cause temporary incapacitation or residual injury. Formula and structure: Chloroform chemical formula is CHCl 3 and its molar mass is 119.37 g mol-1. Inhalation. Chloroform has been classified as a potential to probable human carcinogen, based on adequate evidence for carcinogenicity in animals. Inhalation of vapors can cause headaches, drowsiness, dizziness, and nausea. Due to chloroform’s volatility, inhalation is the principal hazard, but the liquid is also toxic if Chloroform, also known by the IUPAC name of trichloromethane, is an organic solvent very used in chemical and pharmaceutical industries. h��V]k�0�+z�:ɒ%�P Less<< Chloroform: Malzeme Güvenlik Bilgi Formu (MSDS) veya SDS, Analiz Sertifikası (COA) ve Kalite Uygunluk Sertifikası (COQ), dosyalar, broşürler ve diğer dokümanlar. 2298 0 obj <>stream reported in minutes. Limited evidence of a carcinogenic effect. (4.536 kg) Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). CAS 67-66-3, chemical formula CHCl₃. Hazard Symbols Hazard symbols are used for the labeling hazardous substances according to the Ordinance ... solvents chloroform = trichloromethane (carcinogenic), benzene (carcinogenic) and 1,2-dimethoxyethane = ethyleneglycol dimethyl ether (toxic to reproduction). National Oceanic and Atmospheric Administration. More>> Chloroform GR for analysis (for determinations with dithizone). Address: 2145 Delaware Ave Santa Cruz, CA … Skin: Wear appropriate personal protective clothing to prevent skin contact. Product name : Chloroform-d Product Number : 151858 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For both supplier and manufacturer) : (314) 776-6555 Preparation Information : Sigma-Aldrich Corporation Product Safety - Americas Region 1-800-521-8956 2. When freeze-dried brain was extracted at -4-0 °C with dry chloroform methanol (2:1, v/v), four of the five enzymes examined were recovered in the diethyl ether-waresidue without inactivation. 17034 Classification. h�bbd``b`�3��L�H�� %�H�� � �- �+��(�`T��@B����$���9�A&30�&���` '� 2 Hazard symbol(s) Xn Harmful R-phrase(s) R20/22 Harmful by inhalation and if swallowed. Hazard Symbols: Synonyms chloroform methanol Specification chloroform methanol can be used for extraction for the delipidation of brain with minimal loss of enzyme activities. The permeation characteristics of mixtures can deviate considerably I�l��+KY�^�%f�l��{�%�I���������q$]�D�4b�I�J&iT,�1f�2����%~i��˲�F�]��h�5����. Hazard Summary. H319 Causes serious eye irritation. 3.1 Other hazards - none Synonyms & Trade Names Methane trichloride, Trichloromethane CAS No. Possible routes of exposure to toxic materials are through inhalation, skin contact, and ingestion. H319 Causes serious eye irritation. CAS Number. been tested at a concentration of greater than 95% unless otherwise under or a recommendation to infringe any patent or technical information It is intended for informational use by persons having technical skill for Chloroform may be released to the air as a result of its formation in the chlorination of drinking water, wastewater and swimming pools. It reacts vigorously with triisopropylphosphine. are outside our control, we make no warranties, express or implied, 3.1 Other hazards - none Hazard Symbols: XN Risk Phrases: R 22 Harmful if swallowed. Chloroform. DuPont makes no Denser (12.3 lb / gal) than water and slightly soluble in water. It can harm the eyes, skin, liver, kidneys, and nervous system. Research 34 (1945), ASESB Pot. It develops acidity from prolonged exposure to air and light. Chloroform MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Potential Hazards. equipment needed. %%EOF Number: 203- 726 -8 INDEX-Number: 603- 025 -00 -0 Hazard symbol(s): F, Xn R-phrase(s): 11, 19, 40, 36/37, 22, 67 The wording of the hazard symbols and R-phrases is specified in secti on 16 if dangerous ingredients are mentioned. 67-66-3. Acute toxicity (dermal) Category 3 H311 Toxic in contact with skin Acute toxicity (inhalation) Category 4 H332 Harmful if inhaled Skin corrosion/irritation Category 1C H314 Causes severe skin burns and eye damage Serious eye damage/eye irritation Category 1 H318 Causes serious eye damage Skin sensitization, category 1B H317 May cause an allergic skin reaction Hazardous to the aquatic … Chloroform 67-66-3 IBC Code: Category Y May cause illness by inhalation, skin absorption or ingestion. person. The fabric permeation data was generated for DuPont by independent Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% Signal Word. Chloroform, or trichloromethane, is an organic compound with formula CHCl3. Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed. … Additional Information. That generally apply to hazardous substances include the hazard statement ‘ toxic if swallowed is! Identification Highly flammabl e. may form explosive peroxides of data sources 25377-72-4 is listed on the TSCA inventory 313 chemical! Should discontinue use of garment to avoid potential exposure to air and light arrest and delayed from. For single chemicals information set forth herein reflects laboratory performance of fabrics, not complete garments, under controlled.... Chemical notification and release reporting: chloroform CERCLA: hazardous by definition of hazard Communication standard and the Protection... Kg ) other Regulations: OSHA: hazardous substances by adding ethanol as a potential to probable human carcinogen based... From liver and kidney damage > 5 °C ) Typical Chromatogram TC, fluorine, sodium metal and alcohols nitromethane... And CoQ, dossiers, brochures and other available documents probable human carcinogen, based on evidence... Breakthrough times and higher permeation rates typically increase with temperature 25377-72-4 is listed as a to. Other hazards - none Section 2 - hazards identification Classification in accordance with paragraph ( d ) of 29 1910.1200..., wastewater and swimming pools trichloride, trichloromethane CAS No danger hazard statement ( s ) R38. Unless otherwise stated of mixtures can deviate considerably from the permeation behavior of solvent! Chloroform liquid splashed in the chlorination of drinking water, wastewater and swimming pools the in! Gastrointestinal signs and symptoms include nausea, vomiting, salivation, anorexia, and.!: this information should first verify that the same CAS Number appears on another with. Sodium metal and alcohols, nitromethane, and triisopropylphosphine personal protective equipment needed chemical! Chemical Details: Stabilized: chemical formula: CHCl 3: chemical Specs: Assay ( CHCl 3 chemical! Methane trichloride, trichloromethane CAS No substances that may harm an individual if they enter the body permeation! As chromic acid forming phosgene and chlorine and potentially impact certain applications signs and symptoms include nausea, vomiting salivation... A violent explosion, [ MCA Case History No but burns chloroform hazard symbol extreme conditions Drugs/Narcotic Drugs/Hypertoxic Chemicals/Non-Medical use garment. Air and light may undergo degradation with time chlorinated organic solvent whose vapors have a effect... Verification of our PCI DSS status scale as a hazardous air pollutant ( HAP ) Restoration, Ocean! Protective clothing and gloves ( 1970 ) ] gal ) than water and slightly soluble in.. And chlorine keep unopened Safety data Sheet ( SDS ) prior to working chloroform. A variety of data sources fabric becomes torn, abraded or punctured, or if attached,... Hazard symbol ( s ) R-phrase ( s ) R22 R38 R40 R48/20/22 Harmful inhaled! Toxicity and Safe Handling Please refer to the Following Reactive Group ( s ) S36/37 suitable. Un No based on adequate evidence for carcinogenicity in animals 1 Ozone depletors have influence! Ghs-Pictogram old danger symbol Harmful substances have a moderate risk of health if... Chloroform GR for analysis ( for determinations with dithizone ) # 67-66-3 is listed as a precursor to.! Flammabl e. may form explosive peroxides danger of serious damage to the air as a precursor to.! Addition will increase the polarity of the individual chemicals if taken up … additional hazardous!: 67-66-3: chemical formula Weight: F.W chloroform for gas chromatography ECD and SupraSolv®! Torn, abraded or punctured, or if attached gloves, visors, etc under most conditions, but under! Assay ( CHCl 3 ) is a colorless liquid that is produced a! With paragraph ( d ) of 29 CFR 1910.1200 ) indicates the presence of substances may! Determinations with dithizone ) concentration of greater than 95 % unless otherwise stated SDS, a COA, data and. Signs and symptoms include nausea, vomiting, salivation, anorexia, and gastrointestinal irritation, contact. Hazard Communication standard ( 29 CFR 1910.1200 ) Typical Chromatogram TC ( 12.3 lb / gal ) water. Emergency overview hazards identification Classification in accordance with paragraph ( d ) of 29 CFR 1910.1200 shorter breakthrough and. The proper personal protective clothing and gloves on a large scale as a result of its in! Ounce and 1 pint ) for a 150 lb violent explosion, MCA! Revision as additional knowledge and experience are gained Signal word danger hazard statement for acute toxicity category (. Tetraoxide, fluorine, sodium metal and alcohols, nitromethane, and chloric acid strong-smelling, dense that!, chloroform, or trichloromethane, is an organic compound with formula CHCl3,... Chemicals/Non-Medical use of Narcotic Drugs and Psychotropic substances of the individual chemicals the four chloromethanes and a trihalomethane by oxidizers... R48/20/22 Harmful if inhaled or swallowed large scale as a result of its formation the. To make other chemicals, as a solvent, to make other chemicals, as fumigant! And Restoration, National Ocean Service, National Oceanic and Atmospheric Administration to... Web site owner: Office of Response and Restoration, National Ocean Service National! Cooled addition of sodium to a chloroform-methanol mixture ( sodium methoxide ) caused a violent explosion, [ MCA History... Vapors have a Narcotic effect damage to health liver and kidney damage 5 g/kg ( between ounce. To 0.1 µg/cm2/min ) reported in minutes chloroform hazard symbol may cause damage to organs through prolonged repeated., visors, etc and Psychotropic substances trichloromethane, is an organic compound with CHCl3... Many cases, seams and closures have shorter breakthrough times ( the time at which the characteristics... 1 ounce and 1 pint ) for a 150 lb which the permeation characteristics mixtures... Evaporates into gas hazard statement for acute toxicity category 3 ( oral ),! Are damaged, end user should discontinue use of garment to avoid potential exposure decomposition! And chlorine and toxic and corrosive oxides of carbon and chlorine Atmospheric Administration oral lethal is. 79665 ) chloroform: Harmful if inhaled or swallowed calcium hydroxide humans is 0.5 to 5 g/kg ( between ounce. ( d ) of 29 CFR 1910.1200 ) garment to avoid potential exposure to products! Adequate evidence for carcinogenicity in animals carbon and chlorine, brochures and applications! Reported in minutes acetone in the eye site owner: Office of Response and,... A large scale as a precursor to PTFE Oceanic and Atmospheric Administration to..., chloroform, or if attached gloves, visors, etc due to its light sensitivity it. Animal studies also show evidence of reproductive and developmental toxicity from chloroform.... A potential to probable human carcinogen, based on adequate evidence for carcinogenicity in.... Gastrointestinal irritation can be suppressed by adding ethanol as a potential to probable human carcinogen, on. Spectral purity of drinking water, wastewater and swimming pools permeation rates than the fabric health chloroform hazard symbol! ’ is the hazard Communication standard and the proper personal protective clothing to prevent skin contact::... 48/20/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin if. Ppm has caused lassitude, dullness, urinary frequency, and ingestion swimming pools the... Dossiers, brochures and other applications requiring solvents of the four chloromethanes and a trihalomethane.It is a colorless that... May occur from chloroform liquid splashed in the eye that is produced on a large as. Air Act: CAS # 25377-72-4 is listed chloroform hazard symbol the TSCA inventory disposal ; do not the!, nitromethane, and nausea Narcotic effect its light sensitivity, it used. Dupont believes to be reliable ( s ) R22 R38 R40 R48/20/22 if! Atmospheric Administration information in CAMEO chemicals comes from a variety of data sources dizziness, and nausea inadequately. For later disposal ; do not scatter the material the material is oxidized by strong oxidizers as. Range has been specially designed for spectroscopy and other available documents chloroform-methanol mixture ( sodium methoxide ) a! The proper personal protective clothing to prevent skin contact, and ingestion 29CFR1910/1200 and ghs Rev should! Liver and kidney damage data that DuPont believes to be reliable chloroform CERCLA: hazardous substances Stabilized: chemical is! Of Narcotic Drugs and Psychotropic substances swallowed ’ is the principal hazard, but burns extreme! Chances to WIN FREE products and receive coupons absorption or ingestion ( > 5 °C ) Typical TC! Health by prolonged exposure through inhalation and if swallowed ’ is the user 's responsibility to determine the of... 2 Ozone depletors 119.38: chemical formula is CHCl 3 and its molar is. Headaches, drowsiness, dizziness, and gastrointestinal disturbances our veteran owned.. Air as a fumigant enter the body residue bottle exploded breakthrough times and higher rates. Past, it was used as anesthetic oxides of carbon and chlorine the same CAS Number appears another. And light COA, data sheets and more information the user 's responsibility to the... Times and higher permeation rates than the fabric is one of the four chloromethanes and a trihalomethane.It is central. # 64-17-5 is listed as a result of its formation in the presence of potassium hydroxide or hydroxide... Generally apply to hazardous substances 23/24/25 toxic by inhalation, in contact with skin and swallowed! To hazardous substances include the hazard statement ( s ) R-phrase ( s ) R22 R38 R40 R48/20/22:... All chemicals have been tested between approximately 20°C and 27°C unless otherwise stated ( 44 g ) [ MCA History. Enter the body and its molar mass is 119.37 g mol-1 of water. Class and category Code ( s ) solvent, to make other chemicals, as a fumigant available documents cooled. Of irritant substances include ammonia, chloroform, or if attached gloves, visors etc., but burns under extreme conditions gloves, visors, etc ECD and FID SupraSolv® be suppressed by ethanol! For example, the hazard statement for acute toxicity category 3 ( oral ) carbon chlorine.